Trimethylsilyl chloride promoted synthesis of a-branched amines by nucleophilic addition of organozinc halides to nitrones

A general procedure for the nucleophilic addition of organo-zinc halides with nitrones in the presence of trimethylsilyl chloride has been developed. Trimethylsilyl chloride was found to be both an indispensable reaction promoter and a ready hydroxylamine protective agent in these reactions. The produced O-(trimethylsilyl)hydroxylamines can be easily reduced into corresponding amines just by a zinc-copper couple in saturated aqueous NH4Cl solutio

Learning relative features through adaptive pooling for image classification

© 2014 IEEE. Bag-of-Feature (BoF) representations and spatial constraints have been popular in image classification research. One of the most successful methods uses sparse coding and spatial pooling to build discriminative features. However, minimizing the reconstruction error by sparse coding only considers the similarity between the input and codebooks. In contrast, this paper describes a novel feature learning approach for image classification by considering the dissimilarity between inputs and prototype images, or what we called reference basis (RB). First, we learn the feature representation by max-margin criterion between the input and the RB. The learned hyperplane is stored as the relative feature. Second, we propose an adaptive pooling technique to assemble multiple relative features generated by different RBs under the SVM framework, where the classifier and the pooling weights are jointly learned. Experiments based on three challenging datasets: Caltech-101, Scene 15 and Willow-Actions, demonstrate the effectiveness and generality of our framework

Fundamental Cycles and Graph Embeddings

In this paper we present a new Good Characterization of maximum genus of a graph which makes a common generalization of the works of Xuong, Liu, and Fu et al. Based on this, we find a new polynomially bounded algorithm to find the maximum genus of a graph

Air quality and emissions in the Yangtze River Delta, China

Regional trans-boundary air pollution has become an important issue in the field of air pollution modeling. This paper presents the results of the implementation of the MM5-CMAQ modeling system in the Yangtze River Delta (YRD) for the months of January and July of 2004. The meteorological parameters are obtained by using the MM5 model. A new regional emission inventory with spatial and temporal allocations based on local statistical data has been developed to provide input emissions data to the MM5-CMAQ modeling system. The pollutant concentrations obtained from the MM5-CMAQ modeling system have been compared with observational data from the national air pollution monitoring network. It is found that air quality in winter in the YRD is generally worse than in summer, due mainly to unfavorable meteorological dispersion conditions. In winter, the pollution transport from Northern China to the YRD reinforces the pollution caused by large local emissions. The monthly average concentration of SO2 in the YRD is 0.026 ± 0.011 mg m−3 in January and 0.017 ± 0.009 mg m−3 in July. Monthly average concentrations of NO2 in the YRD in January and July are 0.021 ± 0.009 mg m−3, and 0.014 ± 0.008 mg m−3, respectively. The monthly average concentration of PM10 in the YRD is 0.080 ± 0.028 mg m−3 in January and 0.025 ± 0.015 mg m−3 in July. Visibility is also a problem, with average deciview values of 26.4 ± 2.95 dcv in winter and 17.6 ± 3.3 dcv in summer. The ozone concentration in the downtown area of a city like Zhoushan can be very high, with the highest simulated value reaching 0.24 mg m−3. In January, the monthly average concentration of O3 in the YRD is 0.052 ± 0.011 mg m−3, and 0.054 ± 0.008 mg m−3 in July. Our results show that ozone and haze have become extremely important issues in the regional air quality. Thus, regional air pollution control is urgently needed to improve air quality in the YRD. doi:10.5194/acp-11-1621-201

Inhibition of Rice Germination by Ustiloxin A Involves Alteration in Carbon Metabolism and Amino Acid Utilization

Ustiloxins are the main mycotoxin in rice false smut, a devastating disease caused by Ustilaginoidea virens. A typical phytotoxicity of ustiloxins is strong inhibition of seed germination, but the physiological mechanism is not clear. Here, we show that the inhibition of rice germination by ustiloxin A (UA) is dose-dependent. The sugar availability in UA-treated embryo was lower while the starch residue in endosperm was higher. The transcripts and metabolites responsive to typical UA treatment were investigated. The expression of several SWEET genes responsible for sugar transport in embryo was down-regulated by UA. Glycolysis and pentose phosphate processes in embryo were transcriptionally repressed. Most of the amino acids detected in endosperm and embryo were variously decreased. Ribosomal RNAs for growth was inhibited while secondary metabolites salicylic acid was also decreased under UA. Hence, we propose that the inhibition of seed germination by UA involves the block of sugar transport from endosperm to embryo, leading to altered carbon metabolism and amino acids utilization in rice plants. Our analysis provides a framework for understanding of the molecular mechanisms of ustiloxins on rice growth and in pathogen infection

An improvement of isochronous mass spectrometry: Velocity measurements using two time-of-flight detectors

Isochronous mass spectrometry (IMS) in storage rings is a powerful tool for mass measurements of exotic nuclei with very short half-lives down to several tens of microseconds, using a multicomponent secondary beam separated in-flight without cooling. However, the inevitable momentum spread of secondary ions limits the precision of nuclear masses determined by using IMS. Therefore, the momentum measurement in addition to the revolution period of stored ions is crucial to reduce the influence of the momentum spread on the standard deviation of the revolution period, which would lead to a much improved mass resolving power of IMS. One of the proposals to upgrade IMS is that the velocity of secondary ions could be directly measured by using two time-of-flight (double TOF) detectors installed in a straight section of a storage ring. In this paper, we outline the principle of IMS with double TOF detectors and the method to correct the momentum spread of stored ions.Comment: Accepted by Nuclear Inst. and Methods in Physics Research,

Mapping the unconventional orbital texture in topological crystalline insulators

The newly discovered topological crystalline insulators (TCIs) harbor a complex band structure involving multiple Dirac cones. These materials are potentially highly tunable by external electric field, temperature or strain and could find future applications in field-effect transistors, photodetectors, and nano-mechanical systems. Theoretically, it has been predicted that different Dirac cones, offset in energy and momentum-space, might harbor vastly different orbital character, a unique property which if experimentally realized, would present an ideal platform for accomplishing new spintronic devices. However, the orbital texture of the Dirac cones, which is of immense importance in determining a variety of materials properties, still remains elusive in TCIs. Here, we unveil the orbital texture in a prototypical TCI Pb$_{1-x}$Sn$_x$Se. By using Fourier-transform (FT) scanning tunneling spectroscopy (STS) we measure the interference patterns produced by the scattering of surface state electrons. We discover that the intensity and energy dependences of FTs show distinct characteristics, which can directly be attributed to orbital effects. Our experiments reveal the complex band topology involving two Lifshitz transitions and establish the orbital nature of the Dirac bands in this new class of topological materials, which could provide a different pathway towards future quantum applications

Kinetic Turbulence in the Terrestrial Magnetosheath: Cluster Observations

We present a first statistical study of subproton and electron scales turbulence in the terrestrial magnetosheath using the Cluster Search Coil Magnetometer (SCM) waveforms of the STAFF instrument measured in the frequency range [1,180] Hz. It is found that clear spectral breaks exist near the electron scale, which separate two power-law like frequency bands referred to as the dispersive and the electron dissipation ranges. The frequencies of the breaks f_b are shown to be well correlated with the electron gyroscale \rho_e rather than with the electron inertial length de. The distribution of the slopes below fb was found to be narrow and peaks near -2.9, while that of the slopes above fb was found broader, peaks near -5.2 and has values as low as -7.5. This is the first time that such steep power-law spectra are reported in space plasma turbulence. These observations provide strong constraints on theoretical modeling of kinetic turbulence and dissipation in collisionless magnetized plasmas.Comment: 13 pages, 6 figures, submitte